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Micheau, C.; Ueda, Yuki; Motokawa, Ryuhei; Akutsu, Kazuhiro*; Yamada, Norifumi*; Yamada, Masako*; Moussaoui, S. A.*; Makombe, E.*; Meyer, D.*; Berthon, L.*; et al.
Journal of Molecular Liquids, 401, p.124372_1 - 124372_12, 2024/05
Supramolecular organization of extractant molecules impacts metal ions separation behavior. Probing bulk and interfacial structures of the relevant systems is expected to provide key insights into the metal ion selectivity and kinetic aspects. The supramolecular features of two solvent extraction systems based on malonamide extractants THMA in toluene and DBMA in n-heptane were studied using small-angle X-ray scattering for the organic bulk phases, as well as interfacial tension and neutron reflectivity measurements for the interfaces. In the bulk solution, THMA forms dimeric/trimeric associates but no aggregates in toluene, while DBMA forms large aggregates in n-heptane. On the other hand, THMA accumulates in a diffuse layer at the interface at high THMA concentration, whereas DBMA forms a compact but thinner layer. After Pd(II) extraction, the thickness of interfacial layers decreases in the case of THMA, and totally vanishes in the case of DBMA. Based on these new structural information, two mechanisms are proposed for Pd(II) and Nd(III) extraction with malonamides. In toluene, THMA associates slightly accumulate in the vicinity of the interface, then coordinate Pd(II) and diffuse into the organic bulk phase. In n-heptane, DBMA aggregates adsorb at the interface then pick up Nd(III) cations in their polar cores and finally diffuse into the bulk.
Kai, Tetsuya; Harada, Masahide; Teshigawara, Makoto; Watanabe, Noboru; Kiyanagi, Yoshiaki*; Ikeda, Yujiro
Nuclear Instruments and Methods in Physics Research A, 550(1-2), p.329 - 342, 2005/09
Times Cited Count：18 Percentile：74.82(Instruments & Instrumentation)Neutronic study was performed on coupled hydrogen moderators to maximize time-integrated and pulse-peak intensities of slow neutrons when a large number of beams was required. The total increased with the number of beams, although the average decreased due to a reflector-missing by the beam extraction holes in the reflector. At a large beam extraction angle (25 degree), the spatial distribution of the vector-flux of neutrons was undesirable for a rectangular shape moderator. As an alternative we proposed a cylindrical shape one, resulting in a much improved spatial distribution. In addition, neutronic performance was calculated as a function of the diameter, indicating the optimal diameter was about 140 mm. The cylindrical one gave higher pulse-peak intensities with narrower pulse widths without penalty in time-integrated intensities and pulse decay characteristics, providing a more uniform angle-dependence. Some explanations are given for the difference in the pulse characteristics between the two. We decided to adopt the cylindrical one for the Japanese spallation neutron source.
Harada, Masahide; Teshigawara, Makoto; Watanabe, Noboru; Kai, Tetsuya; Ikeda, Yujiro
Proceedings of ICANS-XVI, Volume 2, p.697 - 706, 2003/07
For two decoupled moderators in JSNS, optimization studies were performed by model calculations using NMTC/JAM and MCNP-4C codes. The model was based on a realistic Target-Moderator-Reflector Assembly. We assumed a para-hydrogen ratio of 100%. The shape of poisoned and unpoisoned moderators is a canteen type with dimensions of 13
12
6.2
cm
. A decoupling energy of about 1 eV was adopted to meet the user's requests. As a decoupler material we selected silver-indium-cadmium alloy. It was found that for the decoupled moderators, especially the poisoned moderator, pulse broadening due to a finite beam-extraction angle (
) was very serious. Therefore, for the poisoned and the unpoisoned moderators were limited to be 7.5
and 17.5, respectively. Cadmium (Cd) was selected as a poison material due to higher cut-off energy than gadolinium and higher peak intensity with narrower pulse width. The poison plate will be placed at 25 mm from the viewed surface which meets the user's requirements.
Meigo, Shinichiro; Noda, Fumiaki*; Fujimori, Hiroshi*; Ikeda, Yujiro
Proceedings of ICANS-XVI, Volume 3, p.967 - 976, 2003/07
In J-PARC project, spallation target is irradiated by 3 GeV proton beam of 1 MW. Due to hands on maintenance for the proton beam lines, loss of proton beam is limited less than 1 W/m. Since it is difficult to predict the phase space distribution of the proton beam, we decided that the beam line have to be larger acceptance for 324 
mrad, which is determined by the collimator located in the synchrotron. Distortion of proton beam is caused by the by the instability of angle at the extraction of 3-GeV synchrotron, miss alignment of the magnet, and un-uniformity of the magnet field. In this study, the distortion is calculated. In order to fit the conditions, the stability of extraction angles should be kept smaller than 0.2 mrad. As for the magnetic field, it is found that the uniformity should be kept better 5x10
and 2x10
for bending and quadruple magnets, respectively. It is also found the error of alignments should be limited smaller than 1.0 mm and 1.0 mrad.
